Hi all…while there is some information on the effects of backwashing drinking water biofilters with chlorinated water, there are very few papers on backwashing such biofilters with chloraminated water. In a just published paper in WST: Water Supply researchers trying to determine the cause of rapid monochloramine decay observed in treated water concluded that “backwashing of media filters with chloraminated water was found to be an essential contributor to the occurrence of rapid monochloramine decay. Additionally, the severity of the monochloramine demand decreased with time since backwashing. Further testing found that backwashing with chloraminated water can lead to elevated NDMA formation in filter effluent and significantly impairs the capability of the filters to biologically degrade MIB and geosmin.”
Bill
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Cause of rapid monochloramine decay observed in treated water
Sam Hancock, Martin Harris and David Cook
Water Science and Technology: Water Supply Vol. 17, No. 3, p. 752-758.
http://ws.iwaponline.com/content/17/3/752?etoc
ABSTRACT
“Rapid monochloramine decay has been observed in the product water of three River Murray water treatment plants (WTPs). Previous investigations identified that rapid monochloramine decay was microbiological in nature and observed in samples taken after media filtration but was absent in filtered water samples from a fourth WTP of similar design. The filters at the WTP not exhibiting rapid decay are backwashed with filtered non-disinfected water whereas the other WTPs backwash with treated chloraminated water. It was therefore hypothesised that backwashing filters with chloraminated water was the cause of the rapid monochloramine decay. A pilot-scale study was conducted to investigate the impact of backwashing with chloraminated water on the occurrence of microbiologically accelerated monochloramine decay. Additional samples were analysed to assess the impact of chloraminated backwash water on N-Nitrosodimethylamine (NDMA) formation and biological degradation of taste and odour compounds 2-methylisoborneol (MIB) and geosmin in the filter media. Backwashing with chloraminated filtered water was concluded to be the cause of the observed rapid monochloramine decay, with rapid decay observed within 8 weeks for the filters backwashing with chloramines. Additionally, backwashing with chloraminated filtered water was observed to increase NDMA formation and impair the biological degradation performance of MIB and geosmin.”